Performing VT experiments on 500MHz DMX spectrometer.
The case of lower than ambient temperature
* Fill up the Dewar with liquid nitrogen outside of NMR laboratory.
Do not bring any
magnetic Dewars into the NMR area. Follow the safety
rules with handling of liquid
nitrogen.
* Using gloves and eye protection insert carefully and slowly
the heater into the Dewar.
Make sure that O-ring is in proper place. Insertion
should be slow enough that no spray
of liquid nitrogen occurres outside of the Dewar.
Install the clamp that connects the
heater to Dewar.
* Hook up the VT nitrogen hose to the glass Dewar in the
probe. The glass Dewar is very
fragile, please be extremely cautious while working
with it.
* Use the proper spinner turbine for VT experiments. Actually,
the gray fiber glass spinners
are design for such experiments.
* While in xwinnmr software type ‘EDTE
’ command and the EDTE main window appears.
* Make sure that target sample temperature is set to room
temperature.
* Using EDTE menu set maximum
heater power to 15. It is rather rare that higher
value
will be needed. Click “Apply
” and “OK”.
* Make sure that your target temperature does not exceed
the limit of the probe
specifications. Exceeding the probe’s limit temperature
will damage the probe. The
Magnet might also be damaged.
* Set the temperature 5 degrees lower than ambiet. Set the
cooling current to ~35. It is
rather rare that higher current will be needed
* Turn “ON” cooling by pushing
the LN2 “ON/OFF” button on the console. Push
the
heater button ‘ON’ placed
on VT controller. Another heater button “ON/OFF
” that is in
the EDTE menu is not
designed to work.
* Wait until sample temperature is close to target and decrease
it another 5 degrees.
* To get to the final required temperature, proceed in the
steps of no more than 5-8 degree
to avoid thermal and current shock of hardware.
* When the required temperature is achieved wait certain
period of time before you start to
perform NMR experiment to equalize the temperature
across the sample. A 20 –30
minute period of time is usually needed. However,
you may like to find out your own
waiting time for temperature equalization. Do not
move Dewar or touch the hose
connecting it with probe. The hose is cold and stiff
and applying force might break the
probe’s glass Dewar.
* After experiment is finished, decrease the cooling current
to 10 and increase the
temperature in the 5
degree intervals until the room temperature is achieved. Never
introduce the thermal shock to the system by changing
the temperature with too large
intervals.
*Turn off the heater by pushing heater button “
OFF” on VT controller.
* Turn off the cooling by pushing LN2 button “
ON/OFF”.
* Very carefully unhook the hose from probe (first remove
the small clamp before you
touch the hose) and remove the heater from Dewar.
Remember that heater is very cold
and safety precautions for handling of liquid nitrogen
need to be observed.
* Exit the EDTE menu.
* To warm up probe’s electronic and shims to the ambient
conditions an additional
time between 30-120 minutes
is needed. This depend on how long experiment
took place and what was the final temperature. Mark
your VT experiment in
logbook so a next user will be aware about previous
conditions. Consider those
limitation while signing up so the sign up policy
will be obeyed.
*To find out more details, please refer to the Bruker manual that
is available in NMR
laboratory.
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